Cleansing composition comprising an arylated silicone with five phenyl groups

ABSTRACT

The present invention is related to an aqueous cleansing composition especially for keratin fibres such as human hair with shine enhancing effect. Accordingly the subject of the present invention is an aqueous cleansing composition especially for keratin fibres such as human hair comprising at least one anionic surfactant, at least one non-ionic surfactant and at least one amphoteric surfactant at a total concentration of 5 to 50% by weight calculated to total composition, and at least one arylated silicone at a concentration of 0.001 to 2.5% by weight, calculated to total composition.

The present invention is related to an aqueous cleansing compositionespecially for keratin fibres such as human hair with shine enhancingeffect.

Cleansing compositions have been known for many years. Many patentapplications and scientific publications deal with such compositionsaiming at cleansing and especially improving conditioning effectswherein shine enhancing of human hair has gained particular attention.Although this, there is still need for improvement.

Hair shine improvement has been one of the main areas of development.Hair shine is very much related to the surface structure of hair andthis varies very much with the degree of damage either by environmentaleffects or chemical treatment of hair such as permanent shaping oroxidative colouring. Although consumers with healthy non-damaged hairare generally satisfied with hair shine, shine of damaged hair isusually found to be unsatisfactory. There have been studies aimingimproving shine of especially damaged hair.

Present inventors have surprisingly found out that a cleansingcomposition comprising one or more surfactants and at least one arylatedsilicone cleanses hair thoroughly and improves shine and conditions hairexcellently in terms of combability, elasticity, smoothness andsoftness.

Accordingly the subject of the present invention is an aqueous cleansingcomposition especially for keratin fibres such as human hair comprisingat least one anionic surfactant, at least one non-ionic surfactant andat least one amphoteric surfactant at a total concentration of 5 to 50%by weight calculated to total composition, and at least one arylatedsilicone at a concentration of 0.001 to 2.5% by weight, calculated tototal composition.

Compositions of the present invention comprise at least one arylatedsilicone. With the term arylated silicone it is meant that any siliconecompound comprising at least one aryl group such as a phenyl is suitablefor the compositions of the present invention.

Non-limiting suitable examples are phenyl methicone, phenyltrimethicone, diphenyl dimethicone, diphenylsiloxy phenyl trimethicone,tetramethyl tetraphenyl trisiloxane, triphenyl trimethicone, tetramethlytetraphenyl trisiloxane and trimethyl pentaphenyl trisiloxane.

In the preferred embodiment of the present invention, the arylatedsilicone comprises at least 2 phenyl groups, more preferably 3 and mostpreferably 5 phenyl groups in its molecule.

Particularly preferred arylated silicone is trimethyl pentaphenyltrisiloxane available from Dow Corning under the trade name DC PH-1555HRI.

It should be noted that compositions of the present invention can alsocomprise more than one arylated silicone.

Concentration of at least one arylated silicone is in the range of 0.001to 2.5%, preferably 0.005 to 2%, more preferably 0.01 to 1.5 and mostpreferably 0.1 to 1% by weight calculated to total composition. Theconcentrations referred here are total concentration of arylatedsilicones in case the compositions comprise more than one silicone.

Cleansing compositions of the present invention can be in the form ofconventional liquid thickened shampoo, as well in the form of ready touse foam, delivered either from a pump-foamer or from an aerosol bottle.In the case that an aerosol foam preparation is preferred, propellantgas must be added to the formulation. The suitable propellant gasses arecarbondioxide, dimethylether and alkanes such as butane propane or theirmixtures.

Cleansing compositions of the present invention comprise at least oneanionic surfactant, at least one non-ionic surfactant and at least oneamphoteric surfactant at a total concentration range of 5 to 50%,preferably 5 to 40% and more preferably 7.5 to 30%, and most preferably10 to 25% by weight, calculated to the total composition.

Anionic surfactants suitable within the scope of the invention arepreferably present in an amount from 1 to about 30%, preferably 2 to 20%and most preferably 2-15%, and most preferably 2 to 10% by weight,calculated to the total composition.

In principal any anionic surfactant is suitable within the meaning ofthe present invention. Nonlimiting examples are anionic surfactants ofthe sulfate, sulfonate, carboxylate and alkyl phosphate type,especially, of course, those customarily used in shampoo compositions,for example, the known C₁₀-C₁₈-alkyl sulfates, and in particular therespective ether sulfates, for example, C₁₂-C₁₄-alkyl ether sulfate,lauryl ether sulfate, especially with 1 to 4 ethylene oxide groups inthe molecule, monoglyceride (ether) sulfates, fatty acid amide sulfatesobtained by ethoxylation and subsequent sulfatation of fatty acidalkanolamides, and the alkali salts thereof, as well as the salts oflong-chain mono- and dialkyl phosphates constituting mild,skin-compatible detergents.

Additional anionic surfactants useful within the scope of the inventionare α-olefin sulfonates or the salts thereof, and in particular alkalisalts of sulfosuccinic acid semiesters, for example, the disodium saltof monooctyl sulfosuccinate and alkali salts of long-chain monoalkylethoxysulfosuccinates.

Suitable surfactants of the carboxylate type are alkyl polyethercarboxylic acids and the salts thereof of the formula

R₁—(C₂H₄O)_(n)—O—CH₂COOX,

wherein R₁ is a C₈-C₂₀-alkyl group, preferably a C₁₂-C₁₄-alkyl group, nis a number from 1 to 20, preferably 2 to 17, and X is H or preferably acation of the group sodium, potassium, magnesium and ammonium, which canoptionally be hydroxyalkyl-substituted, as well as alkyl amido polyethercarboxylic acids of the general formula

wherein R₁ and X have the above meanings, and n is in particular anumber from 1 to 10, preferably 2.5 to 5.

Such products have been known for some time and are on the market, forexample, under the trade name “AKYPO®” and “AKYPO-SOFT®”.

Also useful are C₈-C₂₀-acyl isethionates, alone or in admixture withother anionic surfactants, as well as sulfofatty acids and the estersthereof.

It is also possible to use mixtures of several anionic surfactants, forexample an ether sulfate and a polyether carboxylic acid or alkylamidoether carboxylic acid.

Further suitable anionic surfactants are also C₈-C₂₂-acylaminocarboxylic acids or the water-soluble salts thereof. Especiallypreferred is N-lauroyl glutamate, in particular as sodium salt, as wellas, for example, N-lauroyl sarcosinate, N—C₁₂-C₁₈-acyl asparaginic acid,N-myristoyl sarcosinate, N-oleoyl sarcosinate, N-lauroyl methylalanine,N-lauroyl lysine and N-lauroyl aminopropyl glycine, preferably in formof the water-soluble alkali or ammonium, in particular the sodium saltsthereof, preferably in admixture with the above-named anionicsurfactants.

The most preferred anionic surfactants within the meaning of the presentinvention are those of alkyl ether sulphates such as lauryl ethersulphate and aminocarboxylic acids such as lauroyl glutamate sodiumsalt.

Further surfactants in the shampoo compositions according to theinvention are nonionic surfactants. Especially suited are alkylpolyglucosides of the general formula

R₂—O—(R₃O)_(n)—Z_(x),

wherein R₂ is an alkyl group with 8 to 18 carbon atoms, R₃ is anethylene or propylene group, Z is a saccharide group with 5 to 6 carbonatoms, n is a number from 0 to 10 and x is a number between 1 and 5.

These alkyl polyglucosides have recently become known in particular asexcellent skin-compatible, foam improving agents in liquid detergentsand body cleansing compositions, and are present in an amount from about1% to 15%, in particular from 1% to 10% by weight, calculated to thetotal composition.

Mixtures of anionic surfactants and alkyl polyglucosides as well as theuse thereof in liquid body cleansing compositions are already known, forexample, from EP-A 70 074. The alkyl polyglucosides disclosed thereinare basically also suited within the scope of the present invention; aswell as the mixtures of sulfosuccinates and alkyl polyglucosidesdisclosed in EP-A 358 216.

Further nonionic surfactant components may be present, for example,long-chain fatty acid dialkanolamides, such as coco fatty aciddiethanolamide and myristic fatty acid diethanolamide, which can also beused as foam enhancers, preferably in amounts from about 1% to about 5%by weight.

Further additionally useful nonionic surfactants are, for example, thevarious sorbitan esters, such as polyethylene glycol sorbitan stearicacid ester, fatty acid polyglycol esters or poly-condensates ofethyleneoxide and propyleneoxide, as they are on the market, forexample, under the trade name “Pluronics®”, as well as fatty alcoholethoxylates.

Further suitable nonionic surfactants are amineoxides which may bepresent in an amount from 0.25% to 5% by weight, calculated to the totalcomposition. Such amineoxides are state of the art, for example C₁₂-0₁₈—alkyl dimethyl amineoxides such as lauryl dimethyl amineoxide,C₁₂-C₁₈-alkyl amidopropyl or -ethyl amineoxides, C₁₂-C₁₈-alkyldi(hydroxyethyl) or (hydroxypropyl) amineoxides, or also amineoxideswith ethyleneoxide and/or propyleneoxide groups in the alkyl chain. Suchamineoxides are on the market, for example, under the trade namesAmmonyx®, “Aromox®” or Genaminox®.

Further nonionic surfactants useful in the compositions according toinvention are C₁₀-C₂₂-fatty alcohol ethoxylates at a concentration of0.5 to 10%, preferably 0.5 to 5% by weight, calculated to totalcomposition. Especially suited are C₁₀-C₂₂-fatty alcohol ethers, thealkyl polyglycol ethers known by the generic terms “Laureth”,“Myristeth”, “Oleth”, “Ceteth”, “Deceth”, “Steareth” and “Ceteareth”according to the CTFA nomenclature, including addition of the number ofethylene oxide molecules, e.g., “Laureth-16”:

The average degree of ethoxylation thereby ranges between about 2.5 andabout 25, preferably about 10 and about 20.

The most preferred non-ionic surfactants are alkyl polyglucosides suchas decyl, cocoyl polyglucoside and ethoxylated fatty alcohols such aslaureth-16.

As further surfactant component, the compositions of the presentinvention comprise amphoteric surfactants, for example in an amount fromabout 0.5% to about 15%, preferably from about 1% to about 10%, byweight, calculated to the total composition. It has especially beenfound out that addition of zwitterionic or amphoteric surfactantsenhances foam feeling in terms of creaminess, foam volume and as well asskin compatibility is improved. For achieving milder formulationsanionic surfactant, especially of sulphate types, to amphotericsurfactant weight ratio should be in the range of 10:1 to 1:1,preferably 5:1 to 1:1.

Useful as such are in particular the various known betaines such asalkyl betaines, fatty acid amidoalkyl betaines and sulfobetaines, forexample, lauryl hydroxysulfobetaine; long-chain alkyl amino acids, suchas cocoaminoacetate, cocoaminopropionate and sodium cocoamphopropionateand -acetate have also proven suitable.

In detail, it is possible to use betaines of the structure

wherein R₄ is a C₈-C₁₈-alkyl group and n is 1 to 3;sulfobetaines of the structure

wherein R₄ and n are same as above;and amidoalkyl betaines of the structure

wherein R₉ and n are same as above.

The most preferred amphoteric surfactants are alkyl betaines such aslauryl betaine and alkyl amido betaines such as cocamidopropyl betaine.

In the preferred form of the present invention, cleansing compositioncomprises at least one anionic surfactant especially of alkyl ethersulphate type, at least one amphoteric surfactant especially alkyl amidoalkyl betaine type and at least one non-ionic surfactant especiyll analkyl polyglucoside. In the most preferred form of the presentinvention, in addition to the above mentioned surfactant the compositioncomprises additionally acyl amino carboxylic acid surfactant especiallysodium lauroyl glutamate.

The composition of the present invention comprises hair-conditioningagents. Conditioning agents can be selected from oily substances,non-ionic substances, cationic amphiphilic ingredients, cationicpolymers or their mixtures.

Oily substances are selected from such as silicone oils, either volatileor non-volatile, natural and synthetic oils. Among silicone oils thosecan be added to the compositions include dimethicone, dimethiconol,polydimethylsiloxane, DC fluid ranges from Dow Corning, natural oilssuch as olive oil, almond oil, avocado oil, weizenkeim oil, ricinus oiland the synthetic oils, such as mineral oil, isopropyl myri-state,palmitate, stearate and isostearate, ° leyl oleate, isocetyl stearate,hexyl laurate, dibutyl adipate, dioctyl adipate, myristyl myristate andoleyl erucate.

Non-ionic conditioning agents may be polyols such as glycerin, glycoland derivatives, polyethyleneglycoles known with trade names CarbowaxPEG from Union Carbide and Polyox WSR range from Amerchol, polyglycerin,polyethyleneglycol mono or di fatty acid esters having general formula

R₅CO(OCH₂CH₂)_(n)OH or

R₅CO(OCH₂CH₂)_(n)OOCR₆

where R₅ and R₆ are independent from each other saturated, unsaturatedor branched or non-branched alkyl chain with 7 to 21 C atoms and n istypically 2-100.

In one of the preferred from of the present invention, cleansingcompositions comprise at least one cationic polymer as conditioningagent. Suitable cationic polymers are those of best known with theirCTFA category name Polyquaternium. Typical examples of thosePolyquaternium 6, Polyquaternium 7, Polyquaternium 10, Polyquaternium11, Polyquaternium 16, Polyquaternium 22 and Polyquaternium 28,Polyquaternium 37.

As well those polymers known with their CTFA category name Quaterniumare suitable. Those are for example Quaternium-8, Quaternium-14,Quaternium-15, Quaternium-18, Quaternium-22, Quaternium-24,Quaternium-26, Quaternium-27, Quaternium-30, Quaternium-33,Quaternium-53, Quaternium-60, Quaternium-61, Quaternium-72,Quaternium-78, Quaternium-80, Quaternium-81, Quaternium-82,Quaternium-83 and Quaternium-84.

It has further been found out that especially those of cationiccellulose type polymers known as Polymer JR type from Amerchol such asPolyquaternium 10 or cationic guar gum known with trade name Jaguar fromRhône-Poulenc and chemically for example Guar hydroxypropyl trimoniumchloride, are preferred ones. Furthermore, chitosan and chitin can alsobe included in the compositions as cationic natural polymers. In thiscontext reference is also made to the cationic polymers disclosed in DE25 21 960, 28 11 010, 30 44 738 and 32 17 059, as well as to theproducts described in EP-A 337 354 on pages 3 to 7. It is also possibleto use mixtures of various cationic polymers.

The most preferred cationic polymers are those of cationic cellulosederivatives, cationic guar gum derivatives, polyquaternium 6 andpolyquaternium 7.

The cationic polymers also include the quaternized products of graftpolymers from organopolysiloxanes and polyethyl oxazolines described inEP-A 524 612 and EP-A 640 643.

Although less preferred cleansing compositions of the present inventionmay comprise additionally one or more cationic surfactant(s) asconditioner presented with the general formula

where R₇ is a saturated or unsaturated, branched or non-branched alkylchain with 8-22 C atoms or

R₁₁CONH(CH₂)_(n)

where R₁₁ is saturated or unsaturated, branched or non-branched alkylchain with 7-21 C atoms and n has value of 1-4,or

R₁₂COO(CH₂)_(n)

where R₁₂ is saturated or unsaturated, branched or non-branched alkylchain with 7-21 C atoms and n has value of 1-4, andR₈ is hydrogen or unsaturated or saturated, branched or non-branchedalkyl chain with 1-4 C atoms or

R₁₁CONH(CH₂)_(n)

or

R₁₂COO(CH₂)_(n)

where R₁₁, R₁₂ and n are same as above.R₉ and R₁₀ are hydrogen or lower alkyl chain with 1 to 4 carbon atoms,and X is anion such as chloride, bromide, methosulfate.

Typical examples of those ingredients are cetyl trimethly ammoniumchloride, stear trimonium chloride, behentrimoinium chloride,stearamidopropyl trimonuim chloride, dioleoylethyl dimethyl ammoniummethosulfate, dioleoylethyl hydroxyethylmonium methosulfate.

The compositions according to the invention may also comprise furtherconditioning substances such as protein hydrolyzates and polypeptides,e.g., keratin hydrolyzates, collagen hydrolyzates of the type“Nutrilan®” or elastin hydrolyzates, as well as also in particular plantprotein hydrolyzates, optionally, cationized protein hydrolyzates, e.g.,“Gluadin®”.

Typical concentration range for any of those conditioners of cationicpolymers, silicon oil and derivatives and cationic surfactants can be0.01-5% by weight, preferably 0.01-3.5% by weight, more preferably0.05-2.5% and most preferably 0.1-1.5% by weight calculated to the totalcomposition.

Further conditioning additives are hair conditioning and/or stylingpolymers. These may be nonionic polymers, preferably alcohol- and/orwater-soluble vinyl pyrrolidone polymers, such as a vinyl pyrrolidonehomopolymers or copolymers, in particular with vinyl acetate. Usefulvinyl pyrrolidone polymers are, e.g., those known by the trade name“Luviskol®”, for example, the homopolymers “Luviskol® K 30, K 60 and K90”, as well as the water- or alcohol-soluble copolymers from vinylpyrrolidone and vinyl acetate, distributed by BASF AG under the tradename “Luviskol® VA 55 respectively VA 64”. Further possible nonionicpolymers are vinyl pyrrolidone/vinyl acetate/vinyl propionate copolymerssuch as “Luviskol® VAP 343”, vinyl pyrrolidone/(meth)acrylic acid estercopolymers, as well as chitosan derivatives.

Amphoteric polymers are found to be useful in conditioning shampoocomposition of the present invention. They are incorporated alone or inadmixture with at least one additional cationic, nonionic or anionicpolymer, particularly copolymers of N-octyl acrylamide, (meth)acrylicacid and tert.-butyl aminoethyl methacrylate of the type “Amphomer®”;copolymers from methacryl oylethyl betaine and alkyl methacrylates ofthe type “Yukaformer®”, e.g., the butyl methacrylate copolymer“Yukaformer® Am75”; copolymers from monomers containing carboxyl groupsand sulfonic groups, e.g., (meth)acrylic acid and itaconic acid, withmonomers such as mono- or dialkyl amino alkyl(meth)acrylates or mono- ordialkyl aminoalkyl(meth)acrylamides containing basic groups, inparticular amino groups; copolymers from N-octyl acryl-amide, methylmethacrylate, hydroxypropyl methacrylate, N-tert.-butylaminoethyl-methacrylate and acrylic acid, as well as the copolymersknown from U.S. Pat. No. 3,927,199, are applicable.

Cleansing composition of the present invention may comprise pearlizingagent. The preferred once are PEG-3 distearate and ethylene glycoldistearate. The concentration of those can typically be from 0.1 to 3%,preferably 0.5 to 2% by weight, calculated to the total composition.These compounds are preferably added to the compositions in admixturewith anionic, nonionic and/or amphoteric surfactants. Such kind ofmixtures are available commercially.

Cleansing composition of the present invention may comprise organicsolvents such as ethanol, propanol, isopropanol, benzyl alcohol,benzyloxyethanol, ethoxydiglycol, alkylene carbonates such as ethylenecarbonate and propylene carbonate, phenoxyethanol, butanol, isobutanol,cyclohexane, cyclohexanol, hexyleneglycol, ethylenecarbonate,propyleneglycol, poypropyleneglycols, ethyleneglycol monoethylether,ethylene glycol monobutyl ether, ethylene glycol monophenyl ether,1-phenylethylalcohol, 2-phenylethylalcohol, o-methoxyphenol. The mostpreferred ones are benzyloxyethanol and polypropylene glycols.Concentration of organic solvents in the shampoo composition should notexceed 5% by weight, preferably in the range of 0.1 to 3%, morepreferably 0.25 to 2.5% by weight calculated to total composition. Itshould be kept in mind that the presence of the organic solvents mayreduce foam performance of the cleansing composition which may becorrected either by carefully adjusting the concentration of organicsolvent or inclresing slightly the concentration of surfactantsespecially of anionic types.

Solubilizers may be added to the compositions especially when oilysubstances are chosen as conditioning agents and fragrance oils withhighly lipophilic properties. Typical solubilizers may be hydrogenatedcastor oil known with the trade mark Cremophor CO series from BASF. Itshould be noted that as well the surfactant mixture can be a goodsolubilizer for fragrance oils. Typical concentration of thesolubilizers can be in the range of 0.01-2% by weight, preferably 0.1-1%by weight, calculated to total composition.

The cleansing composition may contain active ingredients selected fromUV filters, moisturisers, sequestering agents, and natural ingredients.

The moisturizing agents are selected from panthenol, polyols, such asglycerol, polyethylene glycols with molecular weight 200 to 20,000. Themoisturizing ingredients can be included in the conditioner compositionsat a concentration range of 0.01-2.5% by weight calculated to the totalcomposition.

The sequestering agents are preferably selected from polycarboxy acids.The preferred one is ethylene diamine tetraacetic acid, EDTA. Typicaluseful concentration range for sequestering agents is of 0.01-2.5% byweight calculated to the total composition.

The UV filters are those oil and water soluble ones for the purpose ofprotecting hair colour. In other words, anionic and nonionic, oily, UVfilters are suitably used in the compositions of the present invention.Suitable UV-absorbing substances is are: 4-Aminobenzoic acid and theesters and salts thereof, 2-phenyl benzimidazole-5-sulfonic acid and thealkali and amine salts thereof, 4-dimethyl aminobenzoic acid and theesters and salts thereof, cinnamic acid and the esters and saltsthereof, 4-methoxycinnamic acid and the esters and salts thereof,salicylic acid and the esters and salts thereof,2,4-dihydroxybenzophenone, 2,2′,4,4′-tetrahydroxy-benzophenone,2-hydroxy-4-methoxybenzophenone and its 5-sulfonic acid or the sodiumsalt thereof, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone,2-hydroxy-5-chlorobenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone,2,2′-dihydroxy-4,4′-dimethoxy-5,5′-disulfobenzo-phenone or the sodiumsalt thereof, 2-hydroxy-4-octyloxybenzophenone,2-hydroxy-4-methoxy-4′-methylbenzophenone, 3-benzyl-idenecampher,3-(4′-sulfo)-benzyl-idenebornane-2-one and the salts thereof,3-(4′-methyl benzylidene)-DL-campher, and/or polysilicone-15. The amountof the UV-absorber ranges typically from about 0.01% to 2.5%, morepreferably from 0.05% to 1% by weight, calculated to the totalcomposition.

Natural plant extracts are incorporated usually in an amount of about0.01% to about 10%, preferably 0.05% to 7.5%, in particular 0.1% to 5%by weight, calculated as dry residue thereof to the total composition.Suitable aqueous (e.g. steam-distilled) alcoholic or hydro-alcoholicplant extracts known per se are in particular extracts from leaves,fruits, blossoms, roots, rinds or stems of aloe, pineapple, artichoke,arnica, avocado, valerian, bamboo, henbane, birch, stinging nettle,echinacea, ivy, wild angelica, gentian, ferns, pine needles, silverweed, ginseng, broom, oat, rose hip, hamamelis, hay flowers, elderberry,hop, coltsfoot, currants, chamomile, carrots, chestnuts, clover, burrroot, cocoanut, cornflower, lime blossom, lily of the valley, marinealgae, balm, mistletoe, passion flower, ratanhia, marigold, rosemary,horse chestnut, pink hawthorn, sage, horsetail, yarrow, primrose,nettle, thyme, walnut, wine leaves, white hawthorn, etc. Suitable tradeproducts are, for example, various “Extrapone®” products, and“Herbasol®”. Extracts and the preparation thereof are also described in“Hagers Handbuch der pharmazeutischen Praxis”, 4^(th) Ed.

Cleansing compositions of the present invention can also comprisesynthetic mica as a further shine enhancer.

Use of synthetic mica coated with metal oxide or oxides mainly indecorative cosmetics is disclosed in an international patent applicationof Sun Chemical Corporation published with a number WO 2005/065632 A1.In the document synthetic mica and coated synthetic mica with at leastone metal oxide or oxides is disclosed in detail, the content of thedocument is included herewith by reference. It also discloses acleansing composition comprising monoethanolamide surfactant in additionto other surfactants.

Suitable metal oxide or oxides for coating synthetic mica are titaniumdioxide, chromium oxide, ferric oxide or mixtures thereof. In thepresent invention the preferred is synthetic mice coated with titaniumdioxide. Such materials are commercially available from Sun ChemicalCorporation and known with their INCl names Synthetic Fluorphologopite.

The particle size distribution of synthetic mica coated with a metaloxide or oxides is in the range of 1 to 750 μm, preferably 1 to 250 μm,more preferably 1 to 100 μm and most preferably 20 to 95 μm. Theparticle sizes referred are relating to the volume particle sizedistribution meaning that particles found in the coated synthetic micahaving volume particle size in the given ranges.

Concentration of synthetic mica coated with at least metal oxide oroxides is from 0.001 to 10%, preferably 0.05 to 7.5%, more preferably0.1 to 5% and most preferably 0.25 to 2.5% by weight calculated to totalcomposition.

Further in preferred embodiment of the present invention, compositionscomprise at least one direct dye. Suitable direct dyes are of cationic,anionic and neutral nitro dyes. It should be noted that they can also beused in combination with each other. In other words a compositionaccording to present invention can comprise an anionic and a cationicdye as well as an anionic and a nitro dye or a cationic and a nitro dye.Certainly the combination of all three dyestuffs is also possible.

Any cationic direct dye is in principal suitable for the compositions.Examples are Basic Blue 6, Basic Blue 7, Basic Blue 9, Basic Blue 26,Basic Blue 41, Basic Blue 99, Basic Brown 4, Basic Brown 16, Basic Brown17, Natural Brown 7, Basic Green 1, Basic Orange 31, Basic Red 2, BasicRed 12 Basic Red 22, Basic Red 51, Basic Red 76, Basic Violet 1, BasicViolet 2, Basic Violet 3, Basic Violet 10, Basic Violet 14, Basic Yellow57 and Basic Yellow 87.

Any anionic dye is in principal suitable for the compositions. Suitableexamples are such as Acid Black 1, Acid Blue 1, Acid Blue 3, Food Blue5, Acid Blue 7, Acid Blue 9, Acid Blue 74, Acid Orange 3, Acid Orange 6,Acid Orange 7, Acid Orange 10, Acid Red 1, Acid Red 14, Acid Red 18,Acid Red 27, Acid Red 50, Acid Red 52, Acid Red 73, Acid Red 87, AcidRed 88, Acid Red 92, Acid Red 155, Acid Red 180, Acid Violet 9, AcidViolet 43, Acid Violet 49, Acid Yellow 1, Acid Yellow 23, Acid Yellow 3,Food Yellow No. 8, D&C Brown No. 1, D&C Green No. 5, D&C Green No. 8,D&C Orange No. 4, D&C Orange No. 10, D&C Orange No. 11, D&C Red No. 21,D&C Red No. 27, D&C Red No. 33, D&C Violet 2, D&C Yellow No. 7, D&CYellow No. 8, D&C Yellow No. 10, FD&C Red 2, FD&C Red 40, FD&C Red No.4, FD&C Yellow No. 6, FD&C Blue 1, Food Black 1, Food Black 2, DisperseBlack 9 and Disperse Violet 1 and their alkali metal salts such assodium, potassium.

Among those, the preferred anionic dyestuffs are Acid Red 52, AcidViolet 2, Acid Red 33, Acid Orange 4, Acid Red 27 and Acid Yellow 10 andtheir salts. The most preferred anionic dyes are Acid Red 52, AcidViolet 2, Acid Red 33, Acid Orange 4 and Acid Yellow 10, and their salts

Neutral dyes, so called nitro dyes for shading purposes are alsooptionally contained in the compositions. Suitable ones are HC Blue No.2, HC Blue No. 4, HC Blue No. 5, HC Blue No. 6, HC Blue No. 7, HC BlueNo. 8, HC Blue No. 9, HC Blue No. 10, HC Blue No. 11, HC Blue No. 12, HCBlue No. 13, HC Brown No. 1, HC Brown No. 2, HC Green No. 1, HC OrangeNo. 1, HC Orange No. 2, HC Orange No. 3, HC Orange No. 5, HC Red BN, HCRed No. 1, HC Red No. 3, HC Red No. 7, HC Red No. 8, HC Red No. 9, HCRed No. 10, HC Red No. 11, HC Red No. 13, HC Red No. 54, HC Red No. 14,HC Violet BS, HC Violet No. 1, HC Violet No. 2, HC Yellow No. 2, HCYellow No. 4, HC Yellow No. 5, HC Yellow No. 6, HC Yellow No. 7, HCYellow No. 8, HC Yellow No. 9, HC Yellow No. 10, HC Yellow No. 11, HCYellow No. 12, HC Yellow No. 13, HC Yellow No. 14, HC Yellow No. 15,2-Amino-6-chloro-4-nitrophenol, picramic acid,1,2-Diamino-4-nitrobenzol, 1,4-Diamino-2-nitrobenzol,3-Nitro-4-aminophenol, 1-Hydroxy-2-amino-3-nitrobenzol and2-hydroxyethylpicramic acid.

Concentration of one or more direct dyes in total is in the range of0.001 to 5% by weight, preferably 0.01 to 4% more preferably 0.05 to 3%and most preferably 0.1 to 2.5% by weight calculated to totalcomposition.

The viscosity of the cleansing compositions according to the inventionis in the range of 500 and about 20,000 mPa·s at 20° C., preferably1,000 to 10,000, in particular 1,000 to 7,000 mPa·s at 20° C., measuredwith Brookfield or Happier viscosimeters at a shear rate of 10 sec⁻¹.

Viscosity of shampoo compositions can be adjusted with known viscosityenhancers. The preferred ones are PEG-55 propyleneglycol oleate andPEG-18 glyceryl oleate/cocoate known with the trade names Antil® 141 and171, respectively and PEG-160 sorbitan triisostearate known with a tradename Rheodol®. It should be noted that in the case that a composition isdelivered in the form of a foam from a pump-foamer and/or aerosol can,those compositions should not be thickened and have a viscosity valuenot more than 500 mPa·s, more preferably 250 mPa·s measured as mentionedabove at room temperature.

It is self-understood that the shampoos according to the invention maycomprise other substances customarily used in such compositions such aspreservatives, fragrances.

The following examples are to illustrate the invention, but not tolimit. The products according to the invention are prepared by mixingthe individual components in water, whereby it is also possible to usepre-mixtures of various ingredients.

EXAMPLE 1

% by weight Sodium lauryl ether sulphate 8.0 Cocoyl polyglucoside 3.0Cocamidopropyl betaine 3.0 Sodium lauroyl glutamate 1.0 Trimethylpentaphenyl trisiloxane 0.2 Polyquaternium-10 1.0 Citric acid/sodiumhydroxide q.s. to pH 5.5 Preservative, fragrance q.s Water to 100

For comparative purposes the above composition was also produced withoutarylated silicone, Trimethyl pentaphenyl trisiloxane.

The above composition was prepared by combining surfactants with part ofwater and subsequently adding Polyquaternium-10 solution in waterprepared at around 70° C. Afterwards, Trimethyl pentaphenyl trisiloxanewas added and preservative and fragrance was mixed. Finally pH wasadjusted.

The performance of example was compared to the comparative compositionin a half side test with 10 volunteers. Hair of the volunteer wasdivided into 2 and washed with example 1 and comparative compositionusing according to hair length 4 to 6 g of the product. After rinsingboth sides were evaluated by at least 2 hair dressers and by thevolunteer in towel dried and dry state. It was found that the sidewashed with example 1 had more elasticity, more volume and body andespecially significantly more shine. The preferences were generally 8 to2 and for shine 10/0.

Similar results were observed with the examples below.

EXAMPLE 2

% by weight Sodium lauryl ether sulphate 8.0 Laureth - 16 3.0Cocamidopropyl betaine 3.0 Sodium lauroyl glutamate 1.0 Polyquaternium-71.0 Trimethyl pentaphenyl trisiloxane 0.4 PEG-18 glyceryl oleate/cocoate1.0 Citric acid/sodium hydroxide q.s. to pH 5.5 Preservative, fragranceq.s Water to 100

The above composition was prepared in the similar way as example 1.

EXAMPLE 3

% by weight Sodium lauryl ether carboxylate 9.0 Laureth - 16 3.0 Cocoylbetaine 2.0 Sodium lauroyl glutamate 2.0 Polyquaternium-6 1.0 Phenyltrimethicone 0.2 Trimethyl pentaphenyl trisiloxane 0.2 PEG-18 glyceryloleate/cocoate 1.0 Citric acid/sodium hydroxide q.s. to pH 5.0Preservative, fragrance q.s Water to 100

EXAMPLE 4

% by weight Sodium lauryl ether sulphate 8.0 Cocoyl polyglucoside 3.0Cocoamphoacetate 4.0 Polyquaternium-10 1.0 Dimethicone 0.5 Trimethylpentaphenyl trisiloxane 0.2 Basic red 51 0.1 Citric acid/sodiumhydroxide q.s. to pH 5.5 Preservative, fragrance q.s Water to 100

EXAMPLE 5

% by weight Sodium lauryl ether sulfate 9.0 Laureth - 16 3.0 Cocoylbetaine 2.0 Sodium lauroyl glutamate 2.0 Guarhydroxypropyltrimoniumchloride 1.0 PEG-18 glyceryl oleate/cocoate 1.0 Diphenyldimethicone 0.1Trimethyl pentaphenyl trisiloxane 0.3 Basic red 51 0.08 Basic Orange 310.06 Citric acid/sodium hydroxide q.s. to pH 5.0 Preservative, fragranceq.s Water to 100

EXAMPLE 6

% by weight Sodium lauryl ether sulfate 9.0 Laureth - 16 3.0 Cocoylbetaine 2.0 Sodium lauroyl glutamate 2.0 Dimethicone 1.0 Carbomer 1.0Trimethyl pentaphenyl trisiloxane 0.3 Synthetic fluorphologopite 0.5Citric acid/sodium hydroxide q.s. to pH 5.0 Preservative, fragrance q.sWater to 100*: Synthetic fluorphologopite used is commercially available from SunChemical Corporation under the trade name SunShine Glitter White with aparticle size distribution in the range of 20 to 95 μm.

EXAMPLE 7

% by weight Sodium lauryl ether sulfate 9.0 Laureth - 16 3.0 Cocoylbetaine 2.0 Sodium lauroyl glutamate 2.0 Dimethicone 2.5 Carbopol AquaSF1 1.0 Trimethyl pentaphenyl trisiloxane 0.4 Synthetic fluorphologopite0.8 Citric acid/sodium hydroxide q.s. to pH 5.0 Preservative, fragranceq.s Water to 100*: Synthetic fluorphologopite used is commercially available from SunChemical Corporation under the trade name SunShine Glitter White with aparticle size distribution in the range of 20 to 95 μm.

1- A cleansing composition for keratin fibres especially for human haircomprising at least one anionic surfactant, at least one non-ionicsurfactant, at least one amphoteric surfactant present at a totalconcentration of 5 to 50% by weight calculated to total composition, andat least one arylated silicone comprising 5 phenyl groups in itsmolecule and present at a concentration of 0.001 to 2.5% by weightcalculated to total composition 2- The composition according to claim 1wherein the at least one anionic surfactant and the at least oneamphoteric surfactant are present at a weight ratio between 10:1 and1:1. 3- The composition according to claim 1 comprising at least onealkyl ether sulphate type of anionic surfactant, at least one alkylpolyglucoside type of non-ionic surfactant and at least one alkylbetaine type amphoteric surfactant. 4- (canceled) 5- The compositionaccording to claim 4 wherein the at least one arylated silicone istrimethyl pentaphenyl trisiloxane. 6- The composition according tofurther comprising at least one conditioning agent. 7- The compositionaccording claim 6 wherein the conditioning agent is a cationic polymer.8- The composition according to claim 1 further comprising at least onethickener. 9- The composition according claim 8 wherein the thickener isselected from the group consisting of PEG-55 propylene glycol oleate andPEG-18 glyceryl oleate/cocoate. 10- The composition according to claim 1further comprising at least one UV filter. 11- The composition accordingto claim 1 further comprising at least one pearlising agent. 12- Thecomposition according to claim 1 further comprising at least one organicsolvent. 13- The composition according to claim 1 further comprising atleast one direct dye. 14- The composition according to claim 1 furthercomprising at least one natural plant extract. 15- (canceled)